Ch 12-13 Notes

Organic Air Pollutants

Direct contaminants--have deleterious effect on their own

Indirect pollutants--react in air to make harmful compounds
(e.g.Smog formers)

 

Classes of Organic Air Contaminants

Hydrocarbons
Alkanes

Alkenes



Aromatics




Aldehydes and ketones

 

 

Alcohols,

  

 

Phenols,

 

Ethers

 

 

Oxides

 

 

Carboxylic Acids

 

 

Alkyl Halides






Alkenyl Halides

 

 

Aromatic Halides

 

 

 

Organosulfur Compounds





Organonitrogen Compounds

 

Photochemical Smog

 

Oxidizing and Reducing Smogs

  

Influence of Automobiles

 

NO, CO, Hydrocarbons

 

  

Catalytic Converters

 

  

Emission standards

 

Smog Forming Reactions

 

 

 

Methane Reactions

 

 

Smog Formation

 

 

Sources: Natural--

from plants- terpenes and other hydrocarbons








from decomposition of biomass--mostly methane

 Smog Forming Reactions

Methane Reactions

 

 

 

Photochemical Reactions

Wavelengths < 420 nm --> O atoms

 

 

 

Organic free radicals produced-Chain reactions begin, propagate and terminate

 

 

 

 

 

 

NO2 is formed in quantity

 

 

 

SO2 in Smog

 

 

Effects of Smog:

· Health ·

Plants ·

Materials

 

 

Global Warming

 

 

 

 

 

Acid Rain

 

 

 

 

The Ozone Layer

 

 

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