This is one of the webpages of Libarid A. Maljian at the Department of Physics at CSLA at NJIT.
New Jersey Institute of Technology
College of Science and Liberal Arts
Department of Physics
The Earth in Space
Spring 2023
First Examination lecture notes
Introduction to Earth Science
A system is a collection of
seemingly separate parts that are actually interrelated to form a common
whole. For example, the human body has a
nervous system, which includes the brain, the spinal column, and nerves. The brain, the spinal column, and nerves are
not separate. They are all interrelated
and form a common whole: the nervous system.
As another example, the human body has a circulatory system
(cardiovascular system), which includes the heart, arteries, veins, and
capillaries. The heart, arteries, veins,
and capillaries are not separate. They
are all interrelated and form a common whole: the circulatory system (the
cardiovascular system). As yet another example, the Solar System includes the Sun,
planets, and moons. The Sun, planets,
and moons are not separate. They are all
interrelated and form a common whole: the Solar System.
The planet we call Earth is a
system. The Earth’s geosphere is the
solid part of the Earth. The Earth’s
hydrosphere is the totality of all water on Earth. The Earth’s atmosphere is the totality of all
air on Earth. The Earth’s biosphere is
the totality of all life on Earth. The
geosphere, the hydrosphere, the atmosphere, and the biosphere are not separate. These spheres are all interrelated and form a
common whole: the system we call planet Earth.
The topic of this entire course is Earth Science, which is the study of
the system we call planet Earth. In other words, Earth Science is the combination of at least five
sciences: geology (the study of the Earth’s geosphere), oceanography (the study
of the Earth’s hydrosphere), meteorology (the study of the Earth’s atmosphere),
biology (the study of the Earth’s biosphere), and even astronomy (the study of
the Earth’s surroundings, primarily the Sun and the Moon but also the other
planets).
An open system is a system
that exchanges both matter and energy with its surroundings. At the opposite extreme, an isolated system
is a system that does not exchange matter and does not exchange energy with its
surroundings. In between these two
extremes is a closed system, which is a system that exchanges energy with its
surroundings without exchanging matter with its surroundings. Note that it is impossible for a system to
exchange matter with its surroundings without exchanging energy with its
surroundings. In the strictest sense,
planet Earth is an open system since it exchanges both matter and energy with
its surroundings. However, the matter
that the Earth exchanges with its surroundings can be ignored
for most intents and purposes.
Therefore, planet Earth can be assumed to be a
closed system as an excellent approximation for most intents and purposes.
When we say planet Earth
exchanges energy with its surroundings, we mean that the Earth both receives
energy from its surroundings and radiates energy into its surroundings. The Earth even has an internal energy source,
which we will call geothermal energy. By
far, the most important external energy source of planet Earth is the Sun. Fascinatingly, these two energy sources (the
Sun and the geothermal energy) feed or drive different spheres of planet
Earth. In particular, the Earth’s
external energy source (the Sun) feeds the hydrosphere and the atmosphere, whereas
the Earth’s internal energy source (the geothermal energy) feeds the
geosphere. In other words, if God were
to turn off the Sun, oceanographic processes and meteorological processes would
end but geological processes would continue.
Conversely, if God were to turn off the geothermal energy, geological
processes would end but oceanographic processes and meteorological processes
would continue. The biosphere is mostly
fed by or driven by the Sun, but remarkably a small
part of the biosphere is driven by the geothermal energy, as we will discuss
later in the course.
Cartography
A sphere is a geometrical
shape with an equatorial radius and a polar radius that are equal to each
other. An oblate spheroid is a geometrical
shape with an equatorial radius that is larger than its polar radius; in other
words, its polar radius is smaller than its equatorial radius. A prolate spheroid
is a geometrical shape with an equatorial radius that is smaller than its polar
radius; in other words, its polar radius is larger than its equatorial
radius. The true shape of the Earth is
not a sphere because of its rotation.
The Earth is rotating or turning or spinning
around an imaginary line called the Earth’s rotational axis or axis of
rotation. This rotation causes a
centrifugal force that causes the Earth’s Equator to bulge outward. Thus, the true shape of the Earth is an
oblate spheroid. Indeed, every planet,
moon, and star in the universe is rotating which causes a centrifugal force
that causes its equator to bulge outward.
Thus, the true shape of every planet, moon, and star in the universe is
actually an oblate spheroid. Since the
true shape of the Earth is an oblate spheroid, we are actually further from the
center of the Earth if we are standing at the Equator, and we are actually
closer to the center of the Earth if we are standing at either the North Pole
or the South Pole. Nevertheless, the
Earth’s centrifugal force is actually quite weak. In other words, the bulging of the Earth’s
Equator is very small. Therefore,
although the true shape of the Earth is an oblate spheroid, planet Earth can be
assumed to be a sphere as an excellent approximation
for most intents and purposes. Indeed,
we will assume that the Earth is a sphere for the rest of this course.
There are three possible
intersections of a sphere and a plane.
The intersection of a sphere and a plane that cuts the center of the
sphere is called a great circle. A great circle is the largest possible circle
that we can draw on a sphere; the radius of a great circle is equal to the
radius of the entire sphere. The
intersection of a sphere and a tangent plane is a point, the point where the
tangent plane touches the sphere. A
point is actually a circle with a radius equal to zero. In between these two extremes is a small
circle, the intersection of a sphere and a plane between a center-cutting plane
and a tangent plane.
The geographical coordinate system
labels every point on the surface of planet Earth with two numbers: a latitude
and a longitude. A line of latitude is defined as the intersection of the Earth and a plane that
is perpendicular to the Earth’s rotational axis. All lines of latitude are parallel to one
another. For this reason, lines of
latitude are also called parallels. Most lines of latitude are small circles, but
there are three exceptions: the Equator, the North Pole, and the South
Pole. The Equator is the only line of
latitude that is a great circle. The
Equator divides planet Earth into two hemispheres: the northern hemisphere and
the southern hemisphere. Lines of
latitude in the northern hemisphere are measured in
degrees north, and lines of latitude in the southern hemisphere measured in
degrees south. The Equator itself is
zero degrees latitude. The North Pole
and the South Pole are the only lines of latitude that are points. These are the two points where planet Earth
intersects its own rotational axis. The
North Pole is ninety degrees north latitude, and the South Pole is ninety
degrees south latitude. There are four other lines of latitude that have special
names. The Tropic of Cancer is roughly
23˝ degrees north latitude, and the Tropic of Capricorn is roughly 23˝ degrees
south latitude. The Arctic Circle is
roughly 66˝ degrees north latitude, and the Antarctic Circle is roughly 66˝
degrees south latitude. We will discuss
the importance of all of these special lines of latitude later in the course.
A line of longitude is defined as the intersection of the Earth and a plane that
cuts the center of the Earth and is perpendicular to the lines of
latitude. By this definition, all lines
of longitude are great circles. This is
the first significant difference between lines of latitude and lines of
longitude. Whereas most lines of
latitude are small circles, all lines of longitude are great circles. Another significant difference is that lines
of longitude are measured in degrees east or west,
whereas lines of latitude are measured in degrees north or south. If we regard north as up and south as down,
then east will be to the right and west will be to the left. Yet another significant difference is that
lines of longitude are not parallel to one another, whereas lines of latitude
are parallel to one another. Lines of
longitude are not parallel to one another because they all begin together at
the North Pole, they spread apart from one another until they are furthest
apart from one another at the Equator, and they all converge back together at
the South Pole. Whereas lines of
latitude are also called parallels, lines of longitude
are also called meridians. There are
some similarities between lines of latitude and lines of longitude
however. Just as zero degrees latitude
divides planet Earth into two hemispheres, zero degrees longitude also divides
planet Earth into two hemispheres. Zero
degrees latitude is called the Equator, which divides
planet Earth into the northern hemisphere and the southern hemisphere. Similarly, zero degrees longitude is called the Prime Meridian, which divides planet Earth
into the eastern hemisphere and the western hemisphere. However, this reveals yet another difference
between lines of latitude and lines of longitude. Lines of latitude range from zero degrees to
ninety degrees in each hemisphere (north and south), but lines of longitude
range from zero degrees to one hundred and eighty degrees in each hemisphere
(east and west).
The most important difference
between lines of latitude and lines of longitude is that different lines of
longitude are at different times. During
the daytime, the Sun appears to rise in the east and set in the west. During the nighttime, the stars and galaxies
also appear to rise in the east and set in the west. In other words, everything in the universe
appears to rise in the east and set in the west. This is because the Earth is actually
rotating or turning or spinning in the other direction, from west to east. It takes planet Earth one day or twenty-four
hours to complete one full rotation around its rotational axis. Suppose that it is noon at our location on
planet Earth. Noon is when the Sun
appears highest in the sky. However,
another person who is west of our location is at a time before noon, since that
person must wait for planet Earth to rotate from the west to our location where
the Sun appears to be highest in the sky.
Conversely, yet another person who is east of our location is at a time
after noon, since planet Earth has already rotated that person past our
location. We conclude that lines of
longitude to the west are at earlier times, and lines of
longitude to the east are at later times. If we divide three hundred and sixty degrees
(the number of degrees around the entire planet Earth or any full circle) by
twenty-four hours, the result is a simple whole number: fifteen degrees of
longitude per hour of time. In other
words, for every fifteen degrees of longitude we move to the west, we are one
hour earlier in time, and for every fifteen degrees of longitude we move to the
east, we are one hour later in time.
Indeed, humans have divided the entire planet Earth into twenty-four
time zones, each of which is fifteen degrees of longitude wide. The time at the Prime Meridian is called universal time.
In other words, the Prime Meridian is the only line of longitude where
the local time is equal to the universal time.
Every line of longitude in the western hemisphere has a local time that
is earlier than universal time, and every line of longitude in the eastern
hemisphere has a local time that is later than universal time.
If we begin at the Prime
Meridian and move one hundred and eighty degrees to the west, we are twelve
hours earlier, since one hundred and eighty degrees is half of a full circle
and half of twenty-four hours is twelve hours.
Note also that one hundred and eighty degrees divided by fifteen degrees
per hour is indeed twelve hours.
However, if we begin at the Prime Meridian again but instead move one
hundred and eighty degrees to the east, we are twelve hours later. Suppose the local time at the Prime Meridian
(the universal time) is any time whatsoever, such as 03:14 p.m. Twelve hours earlier than 03:14 p.m. is 03:14
a.m., but twelve hours later than 03:14 p.m. is also 03:14 a.m., but the
following morning! Therefore, one
hundred and eighty degrees longitude is the only line of longitude where the
clock time does not change upon crossing it; the day changes instead! This line of longitude is
called the International Date Line.
When we cross the International Date Line from the eastern hemisphere to
the western hemisphere, we cross into the earlier day but remain at the same
clock time. When we cross the
International Date Line from the western hemisphere to the eastern hemisphere,
we cross into the next day but remain at the same clock time. The International Prime Meridian Conference was held in the United States in Washington, D.C., in the
year 1884. At this conference, the major
powers of the world met to agree upon where to draw the Prime Meridian. Whichever choice they would have made for the
Prime Meridian (zero degrees longitude) would have forced the International
Date Line (one hundred and eighty degrees longitude) to end up on the opposite
side of planet Earth from their choice of the Prime Meridian. During that time in human history, the United
Kingdom was the most powerful empire in the world. Therefore, the British representatives at the
conference pressured the other world powers to agree to draw the Prime Meridian
through Greenwich, England. Although
this was partly a politically-motivated choice, the world powers at the time
realized that this was also a logical choice, since drawing the Prime Meridian
through England forces the International Date Line to run through the middle of
the Pacific Ocean. If instead the date
line were to run through a continent, everyone who crosses that date line by
foot or by horse or by train (or by car today) would need to remember that they are now in a different day. This would be too confusing. If the International Date Line runs through
an ocean, the only persons who would need to remember that they are now in a
different day would be persons in a ship who are crossing that ocean, which
took months of time regardless.
Therefore, the major powers of the world have agreed since the year 1884
to draw the Prime Meridian (zero degrees longitude) through Greenwich,
England. This choice forces the
International Date Line (one hundred and eighty degrees longitude) to run through
the middle of the Pacific Ocean. Today,
anyone who flies across the Pacific Ocean in a matter of a few hours must
remember that they are in a different day when they
land at their destination.
A geodesic is the shortest
possible distance between two points on the surface of planet Earth. This is not a straight line, since we cannot
draw a straight line on planet Earth without drilling a tunnel straight through
the planet! The geometrical question of
what is the shortest distance between two points on a sphere is difficult to
prove mathematically. Nevertheless, the
answer to this geometrical question is simple: the shortest distance between
two points on a sphere is an arc of a great circle. Therefore, a geodesic (the shortest distance
between two points on the surface of planet Earth) is an arc of a great circle,
which can be constructed by intersecting planet Earth with a plane that cuts
the center of planet Earth (and the two points of interest, of course). In some cases, the geodesic between two
locations on Earth is intuitive, but in other cases
the geodesic between two locations on Earth is counterintuitive. For example, consider two cities on the same
line of longitude. What is the shortest
distance between these two cities? Since
a geodesic is an arc of a great circle, we must construct a great circle
connecting these two cities on this line of longitude, but every line of
longitude is a great circle, as we
discussed. Therefore, the shortest
distance between two cities on the same line of longitude is an arc of that
line of longitude. As another example,
consider two cities on the Equator. What
is the shortest distance between these two cities? Since a geodesic is an arc of a great circle,
we must construct a great circle connecting these two cities on the Equator,
but the Equator is a great circle, as
we discussed. Therefore, the shortest
distance between two cities on the Equator is an arc of the Equator. As yet another example, consider two cities
on the same line of latitude other than
the Equator. What is the shortest
distance between these two cities? Since
a geodesic is an arc of a great circle, we must construct a great circle
connecting these two cities that are on this line of latitude, but lines of
latitude (other than the Equator) are not
great circles, as we discussed.
Therefore, the shortest distance between two cities on the same line of
latitude (other than the Equator) is not
an arc of that line of latitude. In
particular, consider two cities on the same midlatitude
in the northern hemisphere. To construct
the geodesic between these two cities, we must construct an arc of a great
circle between these two cities. To do
this, we intersect a plane with the center of the Earth (and the two cities, of
course). If these two cities are on the
same midlatitude in the northern hemisphere, then we
must incline that plane so that it intersects with the center of the
Earth. The result is that the geodesic
(the arc of the great circle) between these two cities curves to the north of
the line of latitude connecting them. To
travel from the eastern city to the western city in the shortest distance, we
follow the geodesic northwest and then southwest before finally arriving at the
western city. To travel from the western
city to the eastern city in the shortest distance, we follow the geodesic
northeast and then southeast before finally arriving at the eastern city. As an extreme example of this construction,
consider two cities on the same midlatitude in the
northern hemisphere that happen to be located on opposite sides of planet
Earth. To construct the geodesic between
these two cities, we must construct an arc of a great circle between these two
cities. We again intersect a plane with
the center of the Earth (and the two cities, of course). If these two cities are on the same midlatitude in the northern hemisphere and happen to be
located on opposite sides of planet Earth, then we must incline the plane
vertically (intersecting the North Pole and the South Pole) so that the plane
intersects with the center of the Earth.
The result is that the geodesic (the arc of the great circle) between
these two cities is along the lines of longitude
connecting each city with the North Pole, not along their common midlatitude. To
travel from either city to the other city in the shortest distance, we follow
the city’s line of longitude directly north over the North Pole and then
continue along a line of longitude directly south before finally arriving at
the other city.
Another word for a map is a
projection, and cartography is the study of maps (or projections). A map (or a projection) is
defined as a flat representation of a part of the Earth (or perhaps the
entire Earth). The most important part
of this definition is the word flat. Since a map (or a projection) is a flat representation of a part of the
Earth (or perhaps the entire Earth), this means that a map (or a projection) is
not a true representation of
whichever part of the Earth the map is attempting to represent, since the Earth
is not flat! In other words, there will
always be something wrong with every possible map (or projection).
A conformal projection is a
map that preserves shapes (or angles).
In other words, the shapes of continents, oceans, islands, lakes, and so
on and so forth are all correct on a conformal projection. An equivalent projection is a map that
preserves relative sizes (or relative areas).
In other words, the relative sizes of continents, oceans, islands,
lakes, and so on and so forth are all correct on an
equivalent projection. There is a
mathematical theorem from advanced geometry which
states that it is impossible for a map to be both conformal and
equivalent. In other words, it is
impossible for a map to have shapes and sizes both correct at the same
time. A map can be entirely conformal,
but then it will not be equivalent. A
map can be entirely equivalent, but then it will not
be conformal. A map can be mostly
conformal, but then it will only be a little equivalent. A map can be mostly equivalent, but then it
will only be a little conformal. In
other words, this mathematical theorem from advanced geometry states that the
more conformal a map is, the less equivalent it will be. Conversely, the more equivalent a map is, the
less conformal it will be. Two variables
that behave this way are called incompatible. In other words, this mathematical theorem
from advanced geometry states that conformality and
equivalence are incompatible variables.
Maps are
often constructed by touching a flat paper to planet Earth and
projecting a part of the Earth (or perhaps the entire Earth) onto that flat
paper. This flat paper often touches the
Earth along a circle on planet Earth.
This circle is called the circle of
tangency. There are three different types
of maps based upon the three different possible circles of tangency:
cylindrical projections, conical projections, and planar projections.
A cylindrical projection is a
map that projects the Earth onto a cylinder that touches planet Earth at a
great circle. In other words, a
cylindrical projection has a great circle as the circle of tangency. This great circle is often the Equator, but
not necessarily. Cylindrical projections
are useful for mapping the entire world.
Indeed, maps of the entire world are almost always
cylindrical projections. Here is the
most important question we must ask about a cylindrical projection: is it
conformal or is it equivalent? The
answer is either (our choice). However,
if it is conformal, then it is not equivalent, and if it is equivalent, then it
is not conformal, by the mathematical theorem from advanced geometry. For example, consider the Mercator
projection, named for the Belgian-German cartographer Gerardus Mercator. The Mercator projection is a cylindrical projection
that is conformal, which means that it is not equivalent. In other words, shapes of continents, oceans,
islands, lakes, and so on and so forth are all correct on a Mercator
projection, but relative sizes of continents, oceans, islands, lakes, and so on
and so forth are incorrect on a Mercator projection. As another example, consider the Gall-Peters
projection, named for the Scottish cartographer James Gall and the German
historian Arno Peters. The Gall-Peters
projection is a cylindrical projection that is equivalent, which means that it
is not conformal. In other words,
relative sizes of continents, oceans, islands, lakes, and so on and so forth
are all correct on a Gall-Peters projection, but shapes of continents, oceans,
islands, lakes, and so on and so forth are incorrect on a Gall-Peters
projection.
A conical projection is a map
that projects the Earth onto a cone that touches planet Earth at a small
circle. In other words, a conical
projection has a small circle as the circle of tangency. This small circle is often a line of
latitude, but not necessarily. Conical
projections are useful for mapping the midlatitude
regions of the world. For example, maps
of the contiguous United States are almost always
conical projections. Here is the most
important question we must ask about a conical projection: is it conformal or
is it equivalent? The answer is either
(our choice). However, if it is
conformal, then it is not equivalent, and if it is equivalent, then it is not
conformal, by the mathematical theorem from advanced geometry. For example, consider the Lambert projection,
named for the Swiss-French mathematician and physicist Johann Heinrich
Lambert. The Lambert projection is a
conical projection that is conformal, which means that it is not
equivalent. In other words, shapes of
continents, oceans, islands, lakes, and so on and so forth are all correct on a
Lambert projection, but relative sizes of continents, oceans, islands, lakes,
and so on and so forth are incorrect on a Lambert projection. As another example, consider the Albers
projection, named for the German cartographer Heinrich Albers. The Albers projection is a conical projection
that is equivalent, which means that it is not conformal. In other words, relative sizes of continents,
oceans, islands, lakes, and so on and so forth are all correct on an Albers
projection, but shapes of continents, oceans, islands, lakes, and so on and so
forth are incorrect on an Albers projection.
A planar projection is a map
that projects the Earth onto a tangent plane that touches planet Earth at a
point. In other words, a planar
projection has a point as the circle of tangency. This point is often the North Pole or the
South Pole, but not necessarily. Planar
projections are useful for mapping the polar regions of the world. In particular, maps of the Arctic Ocean (at
the North Pole) or the continent Antarctica (at the South Pole) are almost always planar projections. Here is the most important question we must
ask about a planar projection: is it conformal or is it equivalent? The answer is either (our choice). However, if it is conformal, then it is not
equivalent, and if it is equivalent, then it is not conformal, by the
mathematical theorem from advanced geometry.
For example, the stereographic projection is a planar projection that is
conformal, which means that it is not equivalent. In other words, shapes of continents, oceans,
islands, lakes, and so on and so forth are all correct on a stereographic
projection, but relative sizes of continents, oceans, islands, lakes, and so on
and so forth are incorrect on a stereographic projection. As another example, the gnomonic projection
is a planar projection that is equivalent, which means that it is not
conformal. In other words, relative
sizes of continents, oceans, islands, lakes, and so on and so forth are all
correct on a gnomonic projection, but shapes of continents, oceans, islands,
lakes, and so on and so forth are incorrect on a gnomonic projection.
Whereas a conformal
projection is not equivalent, the equivalence is at least
partially preserved near the circle of tangency. As we move further and further from the
circle of tangency, the equivalence becomes worse and worse, becoming
most severely distorted far from the circle of tangency. Similarly, whereas an equivalent projection
is not conformal, the conformality is
at least partially preserved near the circle of tangency. As we move further and further from the
circle of tangency, the conformality becomes worse
and worse, becoming most severely distorted far from
the circle of tangency.
We emphasize again this
mathematical theorem from advanced geometry: conformality
and equivalence are incompatible variables, meaning that it is impossible for a
map to be both conformal and equivalent.
Although this geometrical theorem is difficult to prove mathematically,
the essential reason for this incompatibility is simple to understand. A map is a flat representation of a part of
the Earth (or perhaps the entire Earth), but the Earth is not flat. Therefore, something is certain to go wrong
if we try to flatten the Earth. On the
other hand, most humans believed that the Earth is flat for thousands of years. Humans believed that the Earth is flat
because the curvature of a sphere is unmistakable if it is small, but the
curvature becomes smaller and smaller as the sphere becomes larger and
larger. More precisely, the curvature of
a sphere is inversely related to its radius (its
size). A small sphere has a large
curvature, while a large sphere has a small curvature. More plainly, a sphere appears to be more and more flat as it becomes larger and
larger. The Earth is so enormous
compared with humans (in other words humans are so tiny compared with planet
Earth) that the Earth appears to be
flat to humans. We conclude that a tiny
patch of planet Earth must be approximately
flat to an excellent approximation.
Therefore, a map of a tiny patch of the Earth (perhaps a city) will be
both conformal and equivalent to an excellent (but still imperfect)
approximation. As we attempt to
construct a map of a larger and larger part of the Earth, conformality
and equivalence become more and more noticeably incompatible. In the limit of attempting to map the entire
world, this mathematical theorem shows its full teeth.
Physical Geography
The Earth is
mostly covered with oceans. A
relatively small fraction of planet Earth is covered
with seven continents: North America, South America, Africa, Europe, Asia,
Australia, and Antarctica. There are
four oceans: the Atlantic Ocean, the Pacific Ocean, the Indian Ocean, and the
Arctic Ocean.
There is a major mountain
range near the west coast of North America: the Rocky Mountains. The tallest mountain in North America is in the
Rocky Mountains: Mount McKinley (Denali), which is in Alaska (United
States). Immediately to the east of the
Rocky Mountains is the Great Plains. A
plain is an area of land with low elevation and shallow relief, whereas a
plateau is an area of land with high elevation and shallow relief. There is a modest mountain range near the
east coast of North America: the Appalachian Mountains. Historically, the longest river in North
America was the Mississippi River, the mouth of which is at the Gulf of Mexico. However, the United States Army Corps of
Engineers has shortened the Mississippi River through channelization to such a
degree over the past two centuries that the Mississippi River is now the second
longest river in North America. The
longest river in North America is currently the Missouri River, the mouth of
which is at the Mississippi River. The
Rio Grande is a river in North America that serves as part of the border
between the United States and Mexico.
The mouth of the Rio Grande is at the Gulf of Mexico. The Saint Lawrence River in North America
serves as part of the border between the United States and Canada. The mouth of the Saint Lawrence River is at
the Atlantic Ocean. The five lakes Lake
Superior, Lake Michigan, Lake Huron, Lake Erie, and Lake Ontario are together called the Great Lakes, which also serve as
part of the border between the United States and Canada. Lake Superior is not only
the largest of the Great Lakes, but it is also the
largest lake in North America. A
peninsula is a body of land that sticks out into a body of water and is therefore surrounded on three sides by water. Florida is an important peninsula in North
America. The Yucatán (in Mexico) is
another important peninsula in North America.
Baja California is yet another important peninsula in North
America. The Sea of Cortez is between
Baja California and Mexico. The Aleutian
Peninsula is another important peninsula in North America. An archipelago is a group or a chain of
islands. The Aleutian Islands is an archipelago
that can be interpreted as a continuation of the
Aleutian Peninsula, since the Aleutian Islands begin where the Aleutian
Peninsula ends. Another important
archipelago is the West Indies to the southeast of North America. The West Indies is itself a collection of
several archipelagoes, including the Greater Antilles (composed of the four
islands Cuba, Hispaniola, Puerto Rico, and Jamaica), the Lesser Antilles, the
Bahamas, and the Bermuda islands. The Caribbean
Sea is to the south of the West Indies, between the West Indies and South
America. The largest coastal inlet in
North America is Hudson Bay. Greenland
is a body of land to the northeast of North America that is too large to be considered an island but is too small to be considered a
continent. A body of land that is
intermediate in size between an island and a continent is
called a microcontinent.
Greenland is not only a microcontinent; it is the second largest
microcontinent in the world. We will
reveal the largest microcontinent in the world shortly. There is a collection of deserts in
southwestern United States and northwestern Mexico that we will collectively
call the Basin and Range. The deserts
that together form the Basin and Range include the Mojave Desert, the Sonoran
Desert, and the Chihuahuan Desert. A strait is a narrow strip of water
connecting two enormous bodies of water.
The Bering Strait is between Alaska (United States) and Chukotka
(Russia) and connects the Bering Sea with the Arctic Ocean. If a strait is a
narrow strip of water connecting two enormous bodies of water, then the
opposite of a strait would be a narrow strip of land connecting two enormous
bodies of land. This is
called an isthmus. An excellent
example of an isthmus is Panama, a narrow strip of land that connects North
America and South America.
There is a major mountain
range near the west coast of South America: the Andes Mountains. The tallest mountain in South America is in
the Andes Mountains: Mount Aconcagua, which is in Argentina. There is a tropical rainforest in northern
South America: the Amazon rainforest, which is mostly in Brazil. There is a desert in southern South America:
the Patagonian Desert, which is mostly in Argentina. The most arid (most dry)
desert in the entire world is in South America: the Atacama desert, which is
mostly in Chile. The longest river in
South America is the Amazon River, which cuts through the Amazon
rainforest. The mouth of the Amazon
River is at the Atlantic Ocean. The
largest lake in South America is Lake Titicaca, which serves as part of the
border between Peru and Bolivia. The
Galápagos Islands is an archipelago in the Pacific Ocean off the coast of
northwestern South America. The Falkland
Islands is an archipelago in the Atlantic Ocean off the coast of southeastern
South America. Tierra del Fuego is an
archipelago off the southern tip of South America. The Strait of Magellan is between the
southern tip of South America and Tierra del Fuego. South America is the closest continent to
Antarctica, since it is only roughly one thousand kilometers between Tierra del
Fuego and the northern tip of the Antarctic Peninsula. The Drake Passage is between Tierra del Fuego
and the Antarctic Peninsula. Both the
Drake Passage and the Strait of Magellan connect the Atlantic Ocean with the
Pacific Ocean.
There is a major mountain
range in northwestern Africa: the Atlas Mountains. The tallest mountain in Africa is not in
northwestern Africa in the Atlas Mountains; it is in southeastern Africa in the
African Rift Valleys: Mount Kilimanjaro.
The second tallest mountain in Africa is also in southeastern Africa in
the African Rift Valleys: Mount Kenya.
Madagascar is a large island off the coast of southeastern Africa. Madagascar is so large that it may be regarded as a microcontinent. The Mozambique Channel separates Madagascar
from Africa. The largest lake in Africa
is Lake Victoria, which serves as part of the border among Uganda, Kenya, and
Tanzania. The largest hot desert in the
world is in northern Africa: the Sahara.
There is also a desert in southern Africa: the Kalahari. There is a tropical rainforest in central
Africa: the Congo rainforest. The Congo
River, which cuts through the Congo rainforest, is the second longest river in
Africa. The mouth of the Congo River is
at the Atlantic Ocean. The longest river
in Africa is the Nile River, which is also the longest river in the entire
world. The mouth of the Nile River is at
the Mediterranean Sea, a large body of water between Africa and Europe. The Mediterranean Sea is actually a
collection of many small seas, including the Aegean Sea, the Adriatic Sea, the
Ionian Sea, and the Tyrrhenian Sea.
There are several large islands in the Mediterranean Sea, including
Cyprus, Crete, Sicily, Sardinia, and Corsica.
The Strait of Gibraltar is between Spain (in Europe) and Morocco (in
Africa) that connects the Mediterranean Sea with the Atlantic Ocean. The Canary Islands is an archipelago in the
Atlantic Ocean off the coast of Morocco.
Iberia is the western most
part of Europe and includes the countries Spain and Portugal. Iberia may be regarded
as a peninsula. Another important
peninsula in Europe is Scandinavia, which includes the countries Norway,
Sweden, and Finland. To the east of
Scandinavia is the Baltic Sea. To the
west of Scandinavia is the Norwegian Sea.
To the southwest of Scandinavia is the North Sea. To the west of the North Sea is the island
Great Britain, which includes England, Wales, and Scotland. The English Channel separates Great Britain
from France on mainland Europe. To the
west of Great Britain is the island Ireland.
The Irish Sea separates Ireland from Great Britain. Further west of Ireland is the island
Iceland. Another important peninsula in
Europe is Italy. The Alps is a major
mountain range that separates Italy from the rest of Europe. The second tallest mountain in Europe is in
the Alps: Mont Blanc. The tallest
mountain in Europe is Mount Elbrus in the Caucasus Mountains, which are between
the Black Sea and the Caspian Sea. The
Caspian Sea is the largest land-enclosed body of water in the world. The Caucasus Mountains are one set of
mountains that separate Europe from Asia.
Another mountain range that separates Europe from Asia is the Ural
Mountains, which separate European Russia from Asian Russia. The longest river in Europe is the Volga, the
mouth of which is at the Caspian Sea.
The second longest river in Europe is the Danube, the mouth of which is
at the Black Sea.
The largest continent in the
world is Asia. Arabia is a part of the
Asian continent and is separated from Africa by the
Red Sea. There is a collection of
deserts in Arabia that we will collectively call the Arabian Desert. India is a part of the Asian continent. The island Sri Lanka is off the southern
coast of India. The Indian Ocean is to
the south of India. The Arabian Sea is
to the west of India. The Bay of Bengal
is to the east of India. India is separated from the rest of Asia by an enormous mountain
range: the Himalayas. The tallest mountain
in the Himalayas is also the tallest mountain in Asia and the tallest mountain
in the entire world: Mount Everest. To
the north of the Himalayas is an enormous plateau: Tibet. To the north of Tibet is a large desert in
China and Mongolia: the Gobi. The
longest river in Asia is the Yangtze River, the mouth of which is at the East
China Sea. Japan is an archipelago off
the east coast of Asia. The Sea of Japan
separates Japan from mainland Asia. The
Philippines is an archipelago off the southeastern coast of Asia. The South China Sea separates the Philippines
from mainland Asia. Taiwan is a large
island between Japan and the Philippines.
The Taiwan Strait separates Taiwan from mainland Asia. Indonesia is a major archipelago between Asia
and Australia.
The smallest continent in the
world is Australia. There is a
collection of deserts in Australia that we will collectively call the Great
Australian Desert. The deserts that together
form the Great Australian Desert include the Great Victoria Desert, the Great
Sandy Desert, the Tanami Desert, the Simpson Desert, and the Gibson
Desert. There is a major mountain range
along the east coast of Australia: the Great Dividing Range. The tallest mountain in Australia is in the
Great Dividing Range: Mount Kosciuszko.
The longest river in Australia is the Murray River, the mouth of which
is at the Indian Ocean. New Zealand
appears to be two islands to the east of Australia, but the New Zealand islands
are actually a part of the largest microcontinent in the world: Zealandia. The Tasman Sea is between Zealandia and
Australia. Tasmania is an island to the
south of eastern Australia. The Bass Strait
separates Tasmania from Australia.
There happens to be an ocean
at the North Pole: the Arctic Ocean.
There happens to be a continent at the South Pole: Antarctica. The tallest mountain in Antarctica is Mount
Vinson. The longest river in Antarctica
is the Onyx River. The closest continent
to Antarctica is South America, since it is only roughly one thousand kilometers
between the northern tip of the Antarctic Peninsula and Tierra del Fuego, an
archipelago off the southern tip of South America. The Drake Passage is between the Antarctic
Peninsula and Tierra del Fuego. The
Drake Passage connects the Atlantic Ocean with the Pacific Ocean.
The Pacific Ocean is the
largest ocean in the world. Hawaii is an
important archipelago in the middle of the Pacific Ocean. Three other archipelagoes in the Pacific
Ocean are Micronesia, Melanesia, and Polynesia.
Atoms, Chemical Bonding, and States of Matter
All materials in the universe
(such as solids, liquids, and gases) are composed of atoms. Atoms are composed of even smaller
particles. The center of the atom is called the nucleus, since the center of anything is often
called its nucleus. For example, the
center of a biological cell is called the cellular
nucleus, and the center of an entire galaxy is called the galactic
nucleus. The center of an atom is more properly called the atomic nucleus, but we will
often simply refer to it as the nucleus.
Surrounding the atomic nucleus are electrons. The atomic nucleus is positively charged, and
electrons are negatively charged. Like
charges repel, and unlike charges attract.
In other words, positive and positive repel, negative and negative
repel, and positive and negative attract.
It is the attraction between the positive nucleus and
the surrounding negative electrons that holds the atom together. The atomic nucleus is composed of even
smaller particles: protons and neutrons.
Protons are positively charged.
In fact, it is because of the protons that the entire atomic nucleus has
a positive charge. Neutrons have zero
electrical charge. In other words,
neutrons are neutral. This is why they are called neutrons!
The number of protons in the
nucleus is the single most important number of the atom. The number of protons in the nucleus is so
important that it is called the atomic number. The atomic
number, which is always the number of protons in the nucleus, is so important
that an atom is named solely based on its atomic
number. For example, every atom in the universe with twelve
protons in its nucleus is considered to be a magnesium
atom. As another example, every atom in the universe with seven
protons in its nucleus is considered to be a nitrogen
atom. We are not saying that the number
of neutrons is irrelevant, nor are we saying that the number of electrons is
irrelevant. The neutrons and the
electrons are quite important. We are
saying that the atomic number is always the number of protons, and the name of
an atom is based only upon its atomic number, the
number of protons.
Consider an atom where the
number of electrons balances the number of protons. Since protons are positive and electrons are
negative, the atom is neutral overall.
Now suppose we add extra electrons to the atom. Since electrons are negative, the atom will
no longer be neutral overall; the atom will now be negative overall. Suppose instead that we removed electrons
from the atom in the first place. Now
the atom will be positive overall. A
charged atom is called an ion. Therefore, changing the
number of electrons results in ions. For
example, consider the sodium atom with the symbol Na. The atomic number of sodium is eleven,
meaning that every sodium atom in the universe has eleven protons. We will make this clear with a subscript
before the atom’s symbol like this: 11Na. If the sodium atom were neutral, it would
have eleven electrons as well, but suppose we add three more electrons. Since electrons are negative, we now have an
ion with a charge of negative three. We
write the charge as a superscript after the name of the atom like this: 11Na3–. Even though
the charge is read negative three, the superscript is
written in the strange way 3–. As another example, consider the aluminum
atom with the symbol Al. The atomic
number of aluminum is thirteen, meaning that every aluminum atom in the
universe has thirteen protons. We make
this clear with a subscript before the atom’s symbol like this: 13Al. If
the aluminum atom were neutral, it would have thirteen electrons as well, but
suppose we remove two of its electrons.
We now have an ion with a charge of positive two. We write the charge as a superscript after
the name of the atom like this: 13Al2+. Even though the charge is
read positive two, the superscript is written in the strange way
2+. A positive ion is
called a cation, and a negative ion is called an anion. In other words, an anion (a negative ion) has
extra electrons, while a cation (a positive ion) is deficient (has lost)
electrons.
If we change the number of
neutrons, we do not get ions, since
neutrons are neutral. So, adding or
removing neutrons does not change the charge at all. If we change the number of neutrons, what we
are changing is the mass of the atom.
The atomic mass of an atom is
the number of protons plus the number of neutrons. We do not include the electrons when
calculating the mass of the atom because an electron is almost two thousand
times less massive than a proton or a neutron.
Thus, electrons contribute a minuscule amount to the mass of an
atom. A proton and a neutron have
roughly equal amounts of mass, which is why we count them equally. When we change the number of neutrons, we are
changing the atomic mass of the atom.
Two atoms with the same atomic number but different atomic mass are called isotopes. Therefore, changing the number of neutrons
results in isotopes. For example,
consider the carbon atom with the symbol C.
The atomic number of carbon is six, meaning that every carbon atom in
the universe has six protons. We make
this clear with a subscript before the atom’s symbol like this: 6C.
However, carbon has three isotopes: carbon-twelve, carbon-thirteen, and
carbon-fourteen. An isotope is named based on its atomic mass. Thus, the numbers twelve, thirteen, and
fourteen are the atomic masses of these isotopes of carbon. We make this clear with a superscript before
the atom’s symbol like this: for carbon-twelve,
for carbon-thirteen, and
for carbon-fourteen. Notice that carbon always has six protons,
but the carbon-fourteen isotope has eight neutrons, since six plus eight equals
fourteen. The carbon-thirteen isotope
has seven neutrons, since six plus seven equals thirteen. The carbon-twelve isotope has six neutrons, since six
plus six equals twelve. As another example, consider the oxygen atom with the symbol
O. The atomic number of oxygen is eight,
meaning that every oxygen atom in the universe has eight protons. We make this clear with a subscript before
the atom’s symbol like this: 8O. However, oxygen has three isotopes:
oxygen-sixteen, oxygen-seventeen, and oxygen-eighteen. An isotope is named
based on its atomic mass. Thus, the
numbers sixteen, seventeen, and eighteen are the atomic masses of these
isotopes of oxygen. We make this clear
with a superscript before the atom’s symbol like this:
for oxygen-sixteen,
for oxygen-seventeen, and
for oxygen-eighteen. Notice that oxygen always has eight protons,
but the oxygen-eighteen isotope has ten neutrons, since eight plus ten equals
eighteen. The oxygen-seventeen isotope
has nine neutrons, since eight plus nine equals seventeen. The oxygen-sixteen isotope has eight neutrons, since
eight plus eight equals sixteen.
Let
us apply everything we have discussed about atoms to the following
examples. Consider the neon atom with
the symbol Ne. Now suppose we write 2–. This neon atom has ten protons, eleven
neutrons, twelve electrons, an atomic number of ten, an atomic mass of
twenty-one, and a charge of negative two.
As another example, consider the boron atom with the symbol B. (There are borons
in this class!) Now suppose we write
3+. This boron atom has five protons, four neutrons, two
electrons, an atomic number of five, an atomic mass of
nine, and a charge of positive three.
Atoms form chemical bonds
with one another. Although there are
several types of weak chemical bonds, there are only three types of strong
chemical bonds: the ionic bond, the covalent bond, and the metallic bond. First, we discuss the ionic bond. Consider a neutral atom that surrenders (or
loses) one or more of its electrons.
This would turn the atom into a positive ion (a cation). Now suppose another neutral atom accepts or
receives the electron(s) that the first atom surrendered. This would turn the second atom into a
negative ion (an anion). Since unlike
charges attract each other, the cation (the positive ion) and the anion (the
negative ion) will attract each other.
This attraction between two oppositely charged ions is
called an ionic bond. A
collection of atoms chemically bonded to each other is called
a molecule, and there are many examples of molecules built from ionic
bonding. For example, a neutral sodium
atom almost always surrenders one of its electrons to
become the sodium cation Na1+. A neutral chlorine atom almost
always accepts one electron to become the chlorine anion Cl1–. If a sodium cation and a chlorine anion
attract each other, they together become the sodium chloride molecule, which we
write as NaCl.
The sodium chloride molecule has a common name: ordinary table
salt. In other words, the salt that we
cook with and that we put on our food is sodium chloride, which is built from ionic bonding.
An ionic bond results when
electrons are transferred from one atom to another,
but electrons can also be shared more or less equally between two atoms. This sharing of electrons between two atoms is called a covalent bond, and there are many examples of
molecules built from covalent bonding.
For example, an oxygen atom may share a pair of electrons with a
hydrogen atom. If such an oxygen atom
shares another pair of electrons with another hydrogen atom, then we have a
molecule with one oxygen atom sharing electrons with two hydrogen atoms. This is a molecule built from covalent
bonding. This molecule is written H2O and has a common name: water. In other words, the water we drink and the
water that composes most of the human body is built
from covalent bonding. Under ordinary
circumstances, an oxygen atom will never remain by itself. Under ordinary circumstances, an oxygen atom
will almost always covalently bond with other
atoms. The oxygen atom will even
covalently bond with another oxygen atom.
Two oxygen atoms covalently bonded with each other is
called the oxygen molecule, which is written O2. This oxygen molecule O2
is the form of oxygen that all humans and all animals must inhale to
survive. All humans and all animals must
exhale carbon dioxide to survive. Carbon
dioxide is another molecule built from covalent bonding and is
written CO2. The
carbon atom often covalently bonds with four atoms at the same time with a
tetrahedral geometry, since the geometrical shape of the resulting molecule is called a tetrahedron.
Remarkably, the silicon atom often covalently bonds with four atoms at
the same time with a tetrahedral geometry as well.
The metallic bond is the
sharing of an enormous number of delocalized electrons among an enormous number
of atoms. This type of bond is called a metallic bond since it is usually how the atoms
of a metal are held together, such as the atoms that compose a sample of pure
aluminum, pure iron, pure nickel, pure copper, pure zinc, pure silver, pure
platinum, pure gold, or pure lead.
Under which circumstances do
we expect ionic bonding, covalent bonding, or metallic bonding? As a gross simplification, all the atoms in
the Periodic Table of Elements can be divided into three
categories: metals, reactive nonmetals, and noble gases. Generally but not strictly, reactive
nonmetals bond with one another covalently, metals bond with one another
metallically, and metals and reactive nonmetals bond with one another ionically. Generally
but not strictly, the noble gases do not participate in any chemical bonding,
which is why the noble gases are also called the inert gases. Caution: this discussion is a gross
simplification. For example, there is a
fourth category of atoms called the metalloids, which have properties
intermediate between the properties of metals and reactive nonmetals.
The three states of matter
are the solid phase, the liquid phase, and the gas phase. A solid is the state of matter at relatively
cold temperatures where the atoms have the least amount of energy. The atoms of a solid have such little energy
that they remain at particular locations within a rigid chemical
structure. Although the atoms can
vibrate, they nevertheless cannot move away from their particular
locations. As a result, a solid has a
definite volume and a definite shape. A
liquid is the state of matter at relatively intermediate temperatures where the
atoms have enough energy to move, but nevertheless the
atoms still chemically bond with each other.
A liquid still has a definite volume, but a liquid has an indefinite
shape; a liquid can flow. A gas is the
state of matter at relatively hot temperatures where the atoms have so much
energy that they can move completely freely from one another. As a result, a gas not only has an indefinite
shape like a liquid but has an indefinite volume as well. The process by which a solid becomes a liquid
is called melting. The reverse of
melting is called freezing, the process by which a
liquid becomes a solid. The process by
which a liquid becomes a gas is called
vaporizing. The reverse of vaporizing is
called condensing, the process by which a gas becomes a liquid. The process by which a solid turns directly
into a gas (skipping the liquid state) is called
subliming. The reverse of subliming is
called deposing, the process by which a gas turns directly into a solid
(skipping the liquid state).
A substance composed of only
one type of atom is called an element. A substance composed of only one type of
molecule (which is itself composed of more than one type of atom) is called a compound.
A substance composed of a variety of different compounds is called a mixture.
At any particular pressure, elements and compounds usually suffer a
phase change at a specific temperature.
In this case, the melting temperature is always the same as the freezing
temperature (since melting and freezing are simply reverse processes of one
another), and the vaporizing temperature is always the same as the condensing temperature
(since vaporizing and condensing are simply reverse processes of one
another). For example, the compound H2O
is ice in the solid phase, liquid water in the liquid phase, and water vapor
(or steam) in the gas phase. At normal
atmospheric pressure, ice melts to liquid water at zero degrees celsius (or thirty-two degrees fahrenheit), but this means that liquid water freezes
to ice also at zero degrees celsius (or thirty-two
degrees fahrenheit).
Similarly, liquid water vaporizes to water vapor (or steam) at one
hundred degrees celsius (or two hundred and twelve
degrees fahrenheit) at
normal atmospheric pressure, but this means that water vapor (or steam)
condenses to liquid water also at one hundred degrees celsius
(or two hundred and twelve degrees fahrenheit) at
normal atmospheric pressure. Caution:
since mixtures are composed of a variety of different compounds, a mixture will
suffer a phase change over a range of different temperatures, even at a
particular pressure.
Libarid A. Maljian homepage at the Department of Physics at CSLA at NJIT
Libarid A. Maljian profile at the Department of Physics at CSLA at NJIT
Department of Physics at CSLA at NJIT
College of Science and Liberal Arts at NJIT
New Jersey Institute of Technology
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